Name: Zirconium Sputtering Target
CAS: 7440-67-7
EC Number: 231-176-9
Chemical Formular: Zr
Appearance: target
Molecular Weight: 91.224 g/mol
Melting Point: 2128 K (1855 °C, 3371 °F)
Boiling Point: 4650 K (4377 °C, 7911 °F)
Density: 6.52 g/cm3
Solubility in water: n/a
Exact Mass: 89.905 g/mol
Monoisotopic Mass: 89.905 g/mol
Topological Polar Surface Area: 0 A^2
Complexity: 0
MATERIAL SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1
GHS Product identifier
| Product name | Zirconium Sputtering Target |
|---|
1.2
Other means of identification
| Product number | – |
|---|---|
| Other names | – |
1.3
Recommended use of the chemical and restrictions on use
| Identified uses | Industrial and scientific research uses. |
|---|---|
| Uses advised against | no data available |
1.4
Supplier’s details
| Company | Elements China Limited |
|---|---|
| Address | Building 2, No.5555, Shenzhuan Hwy, Shanghai , China |
| Telephone | +86-021-3776-2181 |
1.5Emergency phone number
| Emergency phone number | +86-021-3776-2181 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1
Classification of the substance or mixture
Pyrophoric solids, Category 1
Substances and mixtures, which in contact with water, emit flammable gases, Category 1
2.2
GHS label elements, including precautionary statements
| Pictogram(s) |  |
|---|---|
| Signal word | Danger |
| Hazard statement(s) | H250 Catches fire spontaneously if exposed to air H260 In contact with water releases flammable gases which may ignite spontaneously |
| Precautionary statement(s) | |
| Prevention | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P222 Do not allow contact with air. P233 Keep container tightly closed. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… P223 Do not allow contact with water. P231+P232 Handle and store contents under inert gas/….Protect from moisture. |
| Response | P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. P370+P378 In case of fire: Use … to extinguish. |
| Storage | P402+P404 Store in a dry place. Store in a closed container. |
| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
2.3
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1
Substances
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Zirconium Sputtering Target | – | 7440-67-7 | 231-176-9 |
SECTION 4: First-aid measures
4.1
Description of necessary first-aid measures
If inhaled
Fresh air, rest.
Following skin contact
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Rinse mouth.
4.2
Most important symptoms/effects, acute and delayed
no data available
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Fire-fighting measures
5.1
Suitable extinguishing media
Use dry chemical, carbon dioxide or alcohol-resistant foam.
5.2
Specific hazards arising from the chemical
Combustible. Many reactions may cause fire or explosion. Finely dispersed particles form explosive mixtures in air.
5.3
Special protective actions for fire-fighters
Use dry sand, dry powder.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
6.3
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.
7.2
Conditions for safe storage, including any incompatibilities
See Chemical Dangers.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
TLV: 5 mg/m3, as TWA; 10 mg/m3 as STEL; A4 (not classifiable as a human carcinogen).MAK not established but data are available
Biological limit values
no data available
8.2
Appropriate engineering controls
Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety goggles.
Skin protection
Protective gloves.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Solid. |
|---|---|
| Colour | White. |
| Odour | no data available |
| Melting point/freezing point | Remarks:Test substance does not melt. |
| Boiling point or initial boiling point and boiling range | 4377°C(lit.) |
| Flammability | no data available |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | no data available |
| Auto-ignition temperature | no data available |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | In water: 166 g/L. Temperature:10 °C. pH:0.52. Remarks:Without pH adjustment.;169 g/L. Temperature:20 °C. pH:0.48. Remarks:Without pH adjustment.;< 0.4 mg/L. Temperature:10 °C. pH:4.02. Remarks:With pH adjustment to pH 4. |
| Partition coefficient n-octanol/water | no data available |
| Vapour pressure | no data available |
| Density and/or relative density | 1.987. Temperature:20 °C. |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1
Reactivity
no data available
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
Dust explosion possible if in powder or granular form, mixed with air.Reacts violently with borax and carbon tetrachloride when heated. Reacts explosively with alkali metal hydroxides when heated.
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 – rat (female) – > 300 – < 2 000 mg/kg bw.
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
May cause mechanical irritation to the eyes.
STOT-repeated exposure
Repeated or prolonged inhalation of dust particles may cause effects on the lungs.
Aspiration hazard
A harmful concentration of airborne particles can be reached quickly when dispersed.
SECTION 12: Ecological information
12.1
Toxicity
- Toxicity to fish: LL50 – Oncorhynchus mykiss (previous name: Salmo gairdneri) – > 100 mg/L – 96 h. Remarks:Anhydrous form.
- Toxicity to daphnia and other aquatic invertebrates: EC50 – Daphnia magna – > 100 % v/v saturated solution – 48 h.
- Toxicity to algae: EC50 – Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) – 80 % v/v saturated solution – 72 h.
- Toxicity to microorganisms: no data available
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1
UN Number
| ADR/RID: Not dangerous goods.(For reference only, please check.) | IMDG: Not dangerous goods.(For reference only, please check.) | IATA: Not dangerous goods.(For reference only, please check.) |
14.2
UN Proper Shipping Name
| ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: ZNot dangerous goods. (For reference only, please check.) |
14.3
Transport hazard class(es)
| ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
14.4
Packing group, if applicable
| ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
14.5
Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Zirconium Sputtering Target | – | 7440-67-7 | 231-176-9 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | Oct 28, 2020 |
|---|---|
| Revision Date | Oct 28, 2020 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS – The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home - HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en - CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg - Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp - ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Other Information
Other UN numbers: 1358 Zirconium powder; wetted; hazard class 4.1, packaging group II; 1932 Zirconium scrap, hazard class 4.2, packaging group III; 2009 Zirconium, dry, finished metal sheets, wire, strip, hazard class 4.2, packaging group III; 2858 Zirconium, metal sheets, 18-254 microns, hazard class 4.1, packaging group III.Pure Zirconium sponge is pyrophoric and violently explosive when impure.
Any questions regarding this SDS, Please send your inquiry to [email protected]
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.
| Chemical Formular: | Zr |
| PubChem CID: | 23995 |
| IUPAC Name: | zirconium |
| Inchl: | InChI=1S/Zr |
| InChI Key: | QCWXUUIWCKQGHC-UHFFFAOYSA-N |
| Canonical SMILES: | [Zr] |
| Pictogram(s): | n/a |
| Signal: | n/a |
| GHS Hazard Statements: | n/a |
| Hazard Codes: | n/a |
| Risk Codes: | n/a |
| Precautionary Statement Codes: | n/a |
| Flash Point: | n/a |
Zirconium sputter target
n/a
Zirconium is a chemical element with symbol Zr and atomic number 40. The name zirconium is taken from the name of the mineral zircon, the most important source of zirconium. The word zircon comes from the Persian word zargun زرگون, meaning “gold-colored”. It is a lustrous, grey-white, strong transition metal that resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium forms a variety of inorganic and organometallic compounds such as zirconium dioxide and zirconocene dichloride, respectively. Five isotopes occur naturally, three of which are stable. Zirconium compounds have no known biological role.
In powder form, zirconium is highly flammable, but the solid form is much less prone to ignition. Zirconium is highly resistant to corrosion by alkalis, acids, salt water and other agents.
However, it will dissolve in hydrochloric and sulfuric acid, especially when fluorine is present.
Alloys with zinc are magnetic at less than 35 K.
Fiber drums, steel drums, and bulk bags
