Name: Tin Chloride
CAS: 7772-99-8
EC Number: 231-868-0
Chemical Formular: SnCl2
Appearance: White crystalline solid
Molecular Weight: 189.61 g/mol
Melting Point: 247 °C (477 °F; 520 K)
Boiling Point: 623 °C (1,153 °F; 896 K)
Density: 3.95 g/cm3
Solubility in water: 83.9 g/100 ml (0 °C)
Exact Mass: 189.84 g/mol
Monoisotopic Mass: 189.84 g/mol
Topological Polar Surface Area: 0 A^2
Complexity: 2.8
MATERIAL SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1
GHS Product identifier
| Product name | Tin Chloride |
|---|
1.2
Other means of identification
| Product number | – |
|---|---|
| Other names | Tin(II) chloride;STANNOUS CHLORIDE; |
1.3
Recommended use of the chemical and restrictions on use
| Identified uses | Industrial and scientific research uses. |
|---|---|
| Uses advised against | no data available |
1.4
Supplier’s details
| Company | Elements China Limited |
|---|---|
| Address | Building 2, No.5555, Shenzhuan Hwy, Shanghai , China |
| Telephone | +86-021-3776-2181 |
1.5Emergency phone number
| Emergency phone number | +86-021-3776-2181 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1
Classification of the substance or mixture
Corrosive to metals, Category 1
Acute toxicity – Category 4, Oral
Skin corrosion, Sub-category 1B
Skin sensitization, Category 1
Eye irritation, Category 2
Acute toxicity – Category 4, Inhalation
Specific target organ toxicity – single exposure, Category 3
Specific target organ toxicity – repeated exposure, Category 2
Hazardous to the aquatic environment, long-term (Chronic) – Category Chronic 3
2.2
GHS label elements, including precautionary statements
| Pictogram(s) | 
|
|---|---|
| Signal word | Danger |
| Hazard statement(s) | H290 May be corrosive to metals H302+H332 Harmful if swallowed or if inhaled H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H335 May cause respiratory irritation H373 May cause damage to organs through prolonged or repeated exposure H412 Harmful to aquatic life with long lasting effects |
| Precautionary statement(s) | |
| Prevention | P234 Keep only in original packaging. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. |
| Response | P390 Absorb spillage to prevent material damage. P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P316 Get emergency medical help immediately. P321 Specific treatment (see … on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 IF ON SKIN: Wash with plenty of water/… P333+P317 If skin irritation or rash occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P317 Get medical help. P319 Get medical help if you feel unwell. |
| Storage | P406 Store in a corrosion resistant/…container with a resistant inner liner. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. |
| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
2.3
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1
Substances
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Tin Chloride | Tin dichloride | 7772-99-8 | 231-868-0 |
SECTION 4: First-aid measures
4.1
Description of necessary first-aid measures
If inhaled
Fresh air, rest.
Following skin contact
Remove contaminated clothes. Rinse skin with plenty of water or shower.
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Give one or two glasses of water to drink. Refer for medical attention .
4.2
Most important symptoms/effects, acute and delayed
no data available
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Fire-fighting measures
5.1
Suitable extinguishing media
Use dry chemical, carbon dioxide or alcohol-resistant foam.
5.2
Specific hazards arising from the chemical
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
5.3
Special protective actions for fire-fighters
In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
6.3
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.
7.2
Conditions for safe storage, including any incompatibilities
Separated from incompatible materials and food and feedstuffs. Dry.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
TLV: 2 mg/m3, as TWA.EU-OEL: 2 mg/m3 as TWA
Biological limit values
no data available
8.2
Appropriate engineering controls
Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety goggles or eye protection in combination with breathing protection.
Skin protection
Protective gloves.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | white hygroscopic crystalline powder |
|---|---|
| Colour | no data available |
| Odour | no data available |
| Melting point/freezing point | 246-624ºC |
| Boiling point or initial boiling point and boiling range | 652ºC |
| Flammability | no data available |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | 652ºC |
| Auto-ignition temperature | no data available |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | Solubility in water, g/100ml at 20°C: 90 |
| Partition coefficient n-octanol/water | no data available |
| Vapour pressure | no data available |
| Density and/or relative density | 3.95 |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1
Reactivity
no data available
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
Decomposes on heating. This produces toxic and corrosive gases. The substance is a strong reducing agent. It reacts with oxidants such as nitrates and peroxides and bases.
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
The substance is irritating to the eyes and respiratory tract.
STOT-repeated exposure
no data available
Aspiration hazard
A harmful concentration of airborne particles can be reached quickly when dispersed.
SECTION 12: Ecological information
12.1
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1
UN Number
| ADR/RID: UN3260 (For reference only, please check.) | IMDG: UN3260 (For reference only, please check.) | IATA: UN3260 (For reference only, please check.) |
14.2
UN Proper Shipping Name
| ADR/RID: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (For reference only, please check.) | IMDG: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (For reference only, please check.) | IATA: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (For reference only, please check.) |
14.3
Transport hazard class(es)
| ADR/RID: 8 (For reference only, please check.) | IMDG: 8 (For reference only, please check.) | IATA: 8 (For reference only, please check.) |
14.4
Packing group, if applicable
| ADR/RID: I (For reference only, please check.) | IMDG: I (For reference only, please check.) | IATA: I (For reference only, please check.) |
14.5
Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Tin Chloride | Tin dichloride | 7772-99-8 | 231-868-0 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | Oct 12, 2020 |
|---|---|
| Revision Date | Oct 12, 2020 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS – The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home - HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en - CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg - Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp - ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to [email protected]
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.
| Chemical Formular: | SnCl2 |
| PubChem CID: | 24479 |
| IUPAC Name: | dichlorotin |
| Inchl: | InChI=1S/2ClH.Sn/h2*1H;/q;;+2/p-2 |
| InChI Key: | AXZWODMDQAVCJE-UHFFFAOYSA-L |
| Canonical SMILES: | Cl[Sn]Cl |
| Pictogram(s): |    |
| Signal: | Danger |
| GHS Hazard Statements: | H314-H317-H332-H335-H341-H361-H373-H410 |
| Hazard Codes: | C:Corrosive |
| Risk Codes: | R22;R34 |
| Precautionary Statement Codes: | P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 |
| Flash Point: | 652ºC |
Stannous chloride
Tin(2+) dichloride
Tin dichloride
Dichlorotin
Dichlorostannane
Stannous chloride anahydrous
tin protochloride
Used in dyestuff, perfume, mirror making, electroplating, etc.It is also used as ultra-high pressure lubricating oil, bleach, reducing agent, mordant, decolorizing agent and analytical reagent for the determination of silver, arsenic, molybdenum and mercury.Strong reducing agent. Colorimetric determination of silver, lead, arsenic and molybdenum. The activity of inorganic phosphorus and alkaline phosphatase in serum was determined. Phosphorus content in soil and plant was determined by molybdenum blue method. Organic catalyst.
Used as reducing agent, mordant, acid tin, used as main salt.Used in glass mirror industry, as sensitizing agent for silver nitrate plating, make the coating brightness is good, when adding ABS plating, the coating is not easy to fall off.
Tin is a chemical element with the symbol Sn (from Latin: stannum) and atomic number 50.
Tin is a silvery metal that characteristicly has a faint yellow hue. Tin, like indium, is soft enough to be cut without much force.
When a bar of tin is bent the so-called “tin cry” can be heard as a result of sliding tin crystals reforming; this trait is shared by indium, cadmium and frozen mercury.
Tin is a soft, malleable, ductile and highly crystalline silvery-white metal. When a bar of tin is bent, a crackling sound known as the “tin cry” can be heard from the twinning of the crystals.
The chloride ion is the anion (negatively charged ion) Cl−.
It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents.
Chloride salts such as sodium chloride are often very soluble in water.It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating fluid in and out of cells. Less frequently, the word chloride may also form part of the “common” name of chemical compounds in which one or more chlorine atoms are covalently bonded.
Fiber drums, steel drums, and bulk bags
