Element Zirconium
Element Zirconium is a chemical element with symbol Zr and atomic number 40. The name zirconium is taken from the name of the mineral zircon, the most important source of zirconium. The word zircon comes from the Persian word zargun زرگون, meaning “gold-colored”. It is a lustrous, grey-white, strong transition metal that resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Element Zirconium forms a variety of inorganic and organometallic compounds such as zirconium dioxide and zirconocene dichloride, respectively. Five isotopes occur naturally, three of which are stable. Element Zirconium compounds have no known biological role.
In powder form, zirconium is highly flammable, but the solid form is much less prone to ignition. Zirconium is highly resistant to corrosion by alkalis, acids, salt water and other agents.
However, it will dissolve in hydrochloric and sulfuric acid, especially when fluorine is present.
Alloys with zinc are magnetic at less than 35 K.
Names and Identifiers
Chemical Formula: | Zr |
CAS: | 7740-67-7 |
Molecular Weight: | 91.224 g/mol |
EC Number : | 231-176-9 |
MDL Number: | MFCD00011303 |
Color: | Silvery white /grayish-white |
Other Names: | Zircat, Circonio, Zirconium Metal, Zirkonium |
PubChem CID: | 23995 |
IUPAC Name: | zirconium |
Inchl: | InChI=1S/Zr |
InChI Key: | QCWXUUIWCKQGHC-UHFFFAOYSA-N |
Canonical SMILES: | [Zr] |
ICSC Number: | 1405 |
Physical & Chemical Properties
Phase: | Solid |
Density: | 1.01 g/mL at 25 °C |
Boiling Point: | 4377 °C(lit.) |
Melting Point: | 1852 °C(lit.) |
Molecular Formula: | Zr |
Flash Point: | n/a |
Exact Mass: | 89.90470 |
Symbol: | |
Signal Word: | Danger |
Hazard Statements: | H250-H260 |
Precautionary Statements: | P222-P223-P231 + P232-P370 + P378-P422 |
Hazard Codes: | F: Flammable;Xi: Irritant; |
Risk Phrases: | R17 |
Safety Phrases: | S26-S43-S7/8-S36-S36/37/39-S35-S27-S16 |
RIDADR: | UN 2858 4.1/PG 3 |
WGK Germany: | 2 |
RTECS: | ZH7070000 |
Packaging Group: | III |
Hazard Class: | 4.2 |
Naturally occurring isotopes
Isotope | Mass/Da | Natural abundance (atom %) | Nuclear spin (I) | Magnetic moment (μ/μN) |
---|---|---|---|---|
90Zr | 89.9047026 (26) | 51.45 (40) | 0 | |
91Zr | 90.9056439 (26) | 11.22 (5) | 5/2 | -1.30362 |
92Zr | 91.9050386 (26) | 17.15 (8) | 0 | |
94Zr | 93.9063148 (28) | 17.38 (28) | 0 | |
96Zr | 95.908275 (4) | 2.80 (9) | 0 |
Radiosotope data
Isotope | Mass/Da | Half-life | Mode of decay | Nuclear spin | Nuclear magnetic moment |
---|---|---|---|---|---|
86Zr | 85.91647 | 16.5 h | EC to 86Y | 0 | |
87Zr | 86.91482 | 1.73 h | EC to 87Y | 9/2 | |
88Zr | 87.91023 | 83.4 d | EC to 88Y | 0 | |
89Zr | 88.908889 | 3.27 d | EC to 89Y | 9/2 | |
93Zr | 92.906474 | 1.5 x 106 y | β– to 93Nb | 5/2 | |
95Zr | 94.908041 | 64.02 d | β– to 95Nb | 5/2 | |
96Zr | 95.908276 | 3.9 x 1019 y | 2β– to 96Mo | 0 | |
97Zr | 96.910950 | 16.8 h | β– to 97Nb | 1/2 |