Name: Vanadium Oxide Sputtering Target
CAS: 1314-34-7
EC Number: 215-230-9
Chemical Formular: V2O3
Appearance: Black target
Molecular Weight: 149.881 g/mol
Melting Point: 1,940 °C (3,520 °F; 2,210 K)
Boiling Point: n/a
Density: 4.87 g/cm3
Solubility in water: Insoluble
Exact Mass: 149.872658 g/mol
Monoisotopic Mass: 149.872658 g/mol
Topological Polar Surface Area: 43.4 A^2
Complexity: 34.2
MATERIAL SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1
GHS Product identifier
| Product name | Vanadium Oxide Sputtering Target |
|---|
1.2
Other means of identification
| Product number | – |
|---|---|
| Other names | – |
1.3
Recommended use of the chemical and restrictions on use
| Identified uses | Oxidizing/reducing agents |
|---|---|
| Uses advised against | no data available |
1.4
Supplier’s details
| Company | Elements China Limited |
|---|---|
| Address | Building 2, No.5555, Shenzhuan Hwy, Shanghai , China |
| Telephone | +86-021-3776-2181 |
1.5Emergency phone number
| Emergency phone number | +86-021-3776-2181 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1
Classification of the substance or mixture
Eye irritation, Category 2
2.2
GHS label elements, including precautionary statements
| Pictogram(s) |  |
|---|---|
| Signal word | Warning |
| Hazard statement(s) | H319 Causes serious eye irritation |
| Precautionary statement(s) | |
| Prevention | P264 Wash … thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… |
| Response | P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Storage | none |
| Disposal | none |
2.3
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1
Substances
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Vanadium Oxide Sputtering Target | – | 1314-34-7 | 215-230-9 |
SECTION 4: First-aid measures
4.1
Description of necessary first-aid measures
If inhaled
Fresh air, rest.
Following skin contact
Remove contaminated clothes. Rinse skin with plenty of water or shower.
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Rinse mouth. Refer for medical attention .
4.2
Most important symptoms/effects, acute and delayed
Excerpt from ERG Guide 151 [Substances – Toxic (Non-combustible)]: Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Fire-fighting measures
5.1
Suitable extinguishing media
Excerpt from ERG Guide 151 [Substances – Toxic (Non-combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. LARGE FIRE: Water spray, fog or regular foam. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight streams. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
5.2
Specific hazards arising from the chemical
Excerpt from ERG Guide 151 [Substances – Toxic (Non-combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways. (ERG, 2016)
5.3
Special protective actions for fire-fighters
In case of fire in the surroundings, use appropriate extinguishing media.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2
Environmental precautions
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.
6.3
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.
7.2
Conditions for safe storage, including any incompatibilities
Separated from food and feedstuffs.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
MAK: carcinogen category: 2; germ cell mutagen group: 2
Biological limit values
no data available
8.2
Appropriate engineering controls
Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety goggles or eye protection in combination with breathing protection.
Skin protection
Protective gloves.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Vanadium trioxide is a black crystalline solid. Density 4.87 g / cm3. Slightly soluble in water. Irritating to skin and eyes. May be toxic by ingestion. Used to make other chemicals. Used as a catalyst. |
|---|---|
| Colour | no data available |
| Odour | no data available |
| Melting point/freezing point | 690ºC(lit.) |
| Boiling point or initial boiling point and boiling range | no data available |
| Flammability | Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | no data available |
| Auto-ignition temperature | no data available |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | in water, g/100ml at 20°C: 0.01 (very poor) |
| Partition coefficient n-octanol/water | no data available |
| Vapour pressure | no data available |
| Density and/or relative density | 4.87g/mLat 25°C(lit.) |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1
Reactivity
Decomposes on heating. This produces toxic fumes of vanadium oxides.
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
VANADIUM TRIOXIDE is basic. Reacts rapidly with chlorine. soluble in alkalis and in hydrofluoric acid.
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
The substance is irritating to the eyes, skin and respiratory tract.
STOT-repeated exposure
The substance may have effects on the respiratory tract. This may result in chronic rhinitis and chronic bronchitis. This substance is possibly carcinogenic to humans.
Aspiration hazard
A harmful concentration of airborne particles can be reached quickly when dispersed.
SECTION 12: Ecological information
12.1
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1
UN Number
| ADR/RID: UN3285 (For reference only, please check.) | IMDG: UN3285 (For reference only, please check.) | IATA: UN3285 (For reference only, please check.) |
14.2
UN Proper Shipping Name
| ADR/RID: VANADIUM COMPOUND, N.O.S. (For reference only, please check.) | IMDG: VANADIUM COMPOUND, N.O.S. (For reference only, please check.) | IATA: VANADIUM COMPOUND, N.O.S. (For reference only, please check.) |
14.3
Transport hazard class(es)
| ADR/RID: 6.1 (For reference only, please check.) | IMDG: 6.1 (For reference only, please check.) | IATA: 6.1 (For reference only, please check.) |
14.4
Packing group, if applicable
| ADR/RID: I (For reference only, please check.) | IMDG: I (For reference only, please check.) | IATA: I (For reference only, please check.) |
14.5
Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Vanadium Oxide Sputtering Target | – | 1314-34-7 | 215-230-9 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Not Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Not Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | Nov 19, 2020 |
|---|---|
| Revision Date | Nov 19, 2020 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS – The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home - HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en - CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg - Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp - ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Other Information
Depending on the degree of exposure, periodic medical examination is suggested.Respiratory symptoms may be delayed 1 day or more.See ICSC 0596.
Any questions regarding this SDS, Please send your inquiry to [email protected]
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.
| Chemical Formular: | V2O3 |
| PubChem CID: | 518710 |
| IUPAC Name: | oxo(oxovanadiooxy)vanadium |
| Inchl: | InChI=1S/3O.2V |
| InChI Key: | KFAFTZQGYMGWLU-UHFFFAOYSA-N |
| Canonical SMILES: | O=[V]O[V]=O |
| Pictogram(s): |  |
| Signal: | Warning |
| GHS Hazard Statements: | H319-H332 |
| Hazard Codes: | Xn |
| Risk Codes: | R20-36/37/38 |
| Precautionary Statement Codes: | P305 + P351 + P338 |
| Flash Point: | n/a |
Vanadium(III) oxide
Vanadium oxide (V2O3)
Vanadium (III) oxide
DIVANADIUM TRIOXIDE
Vanadium(3)oxide
n/a
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, ductile, malleable transition metal.
The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer (passivation) somewhat stabilizes the free metal against further oxidation.
Vanadium is a trace element that exists in multiple oxidation states and forms complexes with proteins.
Vanadium has not been shown to be an essential element and, indeed, is absorbed poorly. No deficiency state of vanadium has been demonstrated in humans. High doses of vanadium are toxic to animals and can cause neurologic, hematologic, renal and hepatic toxicity. Feeding of high doses to humans causes gastrointestinal upset, but vanadium has not been linked to hepatotoxicity due to dietary intake or environmental exposures in humans.
Vanadium is a compound that occurs in nature as a white-to-gray metal, and is often found as crystals.
Pure vanadium has no smell. It usually combines with other elements such as oxygen, sodium, sulfur, or chloride. Vanadium and vanadium compounds can be found in the earth’s crust and in rocks, some iron ores, and crude petroleum deposits.
Vanadium is mostly combined with other metals to make special metal mixtures called alloys. Vanadium in the form of vanadium oxide is a component in special kinds of steel that is used for automobile parts, springs, and ball bearings. Most of the vanadium used in the United States is used to make steel.
Vanadium is also mixed with iron to make important parts for aircraft engines. Small amounts of vanadium are used in making rubber, plastics, ceramics, and other chemicals.
Oxygen is the chemical element with the symbol O and atomic number 8, meaning its nucleus has 8 protons.
Oxygen is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds.
Dioxygen is used in cellular respiration and many major classes of organic molecules in living organisms contain oxygen, such as proteins, nucleic acids, carbohydrates, and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone.
Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774.
Fiber drums, steel drums, and bulk bags
