Name: Lead Oxide
CAS: 1317-36-8
EC Number: 215-267-0
Chemical Formular: PbO
Appearance: red or yellow powder
Molecular Weight: 223.199 g/mol
Melting Point: 888 °C (1,630 °F; 1,161 K)
Boiling Point: 1,477 °C (2,691 °F; 1,750 K)
Density: 9.53 g/cm3
Solubility in water: 0.017 g/L
Exact Mass: 223.972 g/mol
Monoisotopic Mass: 223.972 g/mol
Topological Polar Surface Area: 17.1 A^2
Complexity: 2
MATERIAL SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1
GHS Product identifier
| Product name | Lead Oxide |
|---|
1.2
Other means of identification
| Product number | – |
|---|---|
| Other names | oxolead;Lead Monoxide;Lead(II) oxide |
1.3
Recommended use of the chemical and restrictions on use
| Identified uses | Industrial and scientific research uses. |
|---|---|
| Uses advised against | no data available |
1.4
Supplier’s details
| Company | Elements China Limited |
|---|---|
| Address | Building 2, No.5555, Shenzhuan Hwy, Shanghai , China |
| Telephone | +86-021-3776-2181 |
1.5Emergency phone number
| Emergency phone number | +86-021-3776-2181 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1
Classification of the substance or mixture
Acute toxicity – Category 4, Oral
Acute toxicity – Category 4, Inhalation
Carcinogenicity, Category 2
Reproductive toxicity, Category 1A
Reproductive toxicity, Additional category for effects on or via lactation
Specific target organ toxicity – repeated exposure, Category 1
Hazardous to the aquatic environment, short-term (Acute) – Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) – Category Chronic 1
2.2
GHS label elements, including precautionary statements
| Pictogram(s) | 
|
|---|---|
| Signal word | Danger |
| Hazard statement(s) | H302 Harmful if swallowed H332 Harmful if inhaled H351 Suspected of causing cancer H360 May damage fertility or the unborn child H362 May cause harm to breast-fed children H372 Causes damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects |
| Precautionary statement(s) | |
| Prevention | P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P203 Obtain, read and follow all safety instructions before use. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… P260 Do not breathe dust/fume/gas/mist/vapours/spray. P263 Avoid contact during pregnancy and while nursing. P273 Avoid release to the environment. |
| Response | P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P317 Get medical help. P318 IF exposed or concerned, get medical advice. P319 Get medical help if you feel unwell. P391 Collect spillage. |
| Storage | P405 Store locked up. |
| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
2.3
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1
Substances
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Lead Oxide | Lead monoxide | 1317-36-8 | 215-267-0 |
SECTION 4: First-aid measures
4.1
Description of necessary first-aid measures
If inhaled
Fresh air, rest.
Following skin contact
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
4.2
Most important symptoms/effects, acute and delayed
no data available
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Fire-fighting measures
5.1
Suitable extinguishing media
Use dry chemical, carbon dioxide or alcohol-resistant foam.
5.2
Specific hazards arising from the chemical
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
5.3
Special protective actions for fire-fighters
In case of fire in the surroundings, use appropriate extinguishing media.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
6.3
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.
7.2
Conditions for safe storage, including any incompatibilities
Separated from food and feedstuffs and incompatible materials. See Chemical Dangers.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
TLV: 0.05 mg/m3, as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans).MAK: carcinogen category: 2; germ cell mutagen group: 3A.EU-OEL: (binding): 0.15 mg/m3 as TWA
Biological limit values
no data available
8.2
Appropriate engineering controls
Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety spectacles.
Skin protection
Protective gloves.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Solid. Powder. |
|---|---|
| Colour | Yellow. |
| Odour | no data available |
| Melting point/freezing point | > 600 °C. Atm. press.:Ca. 1 013 mBar. Remarks:The test item has no melting point at atmospheric pressure up to the final temperature of 600 °C. |
| Boiling point or initial boiling point and boiling range | > 600 °C. Atm. press.:Ca. 1 013 mBar. Remarks:The test item has no boiling point at atmospheric pressure up to the final temperature of 600 °C. |
| Flammability | no data available |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | no data available |
| Auto-ignition temperature | no data available |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | Insoluble in water |
| Partition coefficient n-octanol/water | no data available |
| Vapour pressure | no data available |
| Density and/or relative density | 9.96. Temperature:22.5 °C. |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1
Reactivity
no data available
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
Reacts violently with aluminium powder. Decomposes on heating. This produces toxic fumes.
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: LC50 – rat (male/female) – > 5.05 mg/L air.
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
The substance may have effects on the blood, bone marrow, central nervous system, peripheral nervous system and kidneys. This may result in anaemia, encephalopathy (for example, convulsions), peripheral nerve disease, abdominal cramps and kidney impairment. Causes toxicity to human reproduction or development.
Aspiration hazard
A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
SECTION 12: Ecological information
12.1
Toxicity
- Toxicity to fish: LC50 – Oncorhynchus mykiss (previous name: Salmo gairdneri) – 1 170 µg/L – 96 h. Remarks:(estimated using the conversion equation according to Blust (2010); measured total LC50 values was 1170 µg/L).
- Toxicity to daphnia and other aquatic invertebrates: NOEC – other aquatic mollusc: Crassostrea gigas – >= 1 915 µg/L – 48 h. Remarks:Pb.
- Toxicity to algae: NOEC – Skeletonema costatum – 22.7 µg/L – 96 h.
- Toxicity to microorganisms: IC10 – Micro-organisms living in activated sludge mixed liquor – 2.92 mg/L – 1 h. Remarks:Respiration rate.
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1
UN Number
| ADR/RID: UN2291 (For reference only, please check.) | IMDG: UN2291 (For reference only, please check.) | IATA: UN2291 (For reference only, please check.) |
14.2
UN Proper Shipping Name
| ADR/RID: LEAD COMPOUND, SOLUBLE, N.O.S. (For reference only, please check.) | IMDG: LEAD COMPOUND, SOLUBLE, N.O.S. (For reference only, please check.) | IATA: LEAD COMPOUND, SOLUBLE, N.O.S. (For reference only, please check.) |
14.3
Transport hazard class(es)
| ADR/RID: 6.1 (For reference only, please check.) | IMDG: 6.1 (For reference only, please check.) | IATA: 6.1 (For reference only, please check.) |
14.4
Packing group, if applicable
| ADR/RID: III (For reference only, please check.) | IMDG: III (For reference only, please check.) | IATA: III (For reference only, please check.) |
14.5
Environmental hazards
| ADR/RID: Yes | IMDG: Yes | IATA: Yes |
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Lead Oxide | Lead monoxide | 1317-36-8 | 215-267-0 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | Sep 30, 2020 |
|---|---|
| Revision Date | Sep 30, 2020 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS – The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home - HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en - CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg - Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp - ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Other Information
Depending on the degree of exposure, periodic medical examination is indicated.Do NOT take working clothes home.See ICSC 0052.
Any questions regarding this SDS, Please send your inquiry to [email protected]
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.
| Chemical Formular: | PbO |
| PubChem CID: | 14827 |
| IUPAC Name: | oxolead |
| Inchl: | InChI=1S/O.Pb |
| InChI Key: | YEXPOXQUZXUXJW-UHFFFAOYSA-N |
| Canonical SMILES: | O=[Pb] |
| Pictogram(s): |   |
| Signal: | Danger |
| GHS Hazard Statements: | H302 + H332-H351-H360Df-H362-H372-H410 |
| Hazard Codes: | T,N |
| Risk Codes: | R61-20/22-33-50/53-62 |
| Precautionary Statement Codes: | P201-P260-P263-P280-P301 + P312 + P330-P308 + P313 |
| Flash Point: | n/a |
Lead monoxide
Lead(2+) oxide
Lead protoxide
Plumbous oxide
lead(2+) oxygen(2-)
Lead monooxide
Litharge
Massicot
CAS 79120-33-5
n/a
Lead (/ˈlɛd/) is a chemical element with the symbol Pb (from the Latin plumbum) and atomic number 82.
It is a heavy metal that is denser than most common materials.
Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is silvery with a hint of blue; it tarnishes to a dull gray color when exposed to air.
Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements.
Oxygen is the chemical element with the symbol O and atomic number 8, meaning its nucleus has 8 protons.
Oxygen is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds.
Dioxygen is used in cellular respiration and many major classes of organic molecules in living organisms contain oxygen, such as proteins, nucleic acids, carbohydrates, and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone.
Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774.
Fiber drums, steel drums, and bulk bags
