Element Bromine
It is a chemical element with symbol Br and atomic number 35.
Element Bromine is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas.
Its properties are thus intermediate between those of chlorine and iodine.
Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek βρῶμος (“stench”), referencing its sharp and disagreeable smell.
Names and Identifiers
Chemical Formula: | Br |
CAS: | 7726-95-6 |
Molecular Weight: | 159.808g/mol |
EC Number : | 231-778-1 |
MDL Number: | MFCD00010896 |
Color: | red-brown |
Other Names: | Brom, Brome, Bromo |
PubChem CID: | 24408 |
IUPAC Name: | Bromine |
Inchl: | InChI=1S/Br |
InChI Key: | WKBOTKDWSSQWDR-UHFFFAOYSA-N |
Canonical SMILES: | [Br] |
ICSC Number: | 0107 |
Physical & Chemical Properties
Phase: | Lquid |
Density: | 3.1028 g/cm³ |
Boiling Point: | 332.0 K (58.8 °C, 137.8 °F) |
Melting Point: | 265.8 K (−7.2 °C, 19 °F) |
Molecular Formula: | Br |
Flash Point: | 113 °C |
Exact Mass: | 157.836655 |
Symbol: | |
Signal Word: | Danger |
Hazard Statements: | H314-H330-H400 |
Precautionary Statements: | P260-P273-P280-P284-P305 + P351 + P338-P310 |
Hazard Codes: | T+,C,N,T |
Risk Phrases: | R26;R35;R50 |
Safety Phrases: | S26-S45-S61-S7/9-S36/37/39-S28-S53 |
RIDADR: | UN 1744 8/PG 1 |
WGK Germany: | 2 |
RTECS: | EF9100000 |
Packaging Group: | I |
Hazard Class: | 8 |
Both Bromine isotopes are used in nuclear medicine.
Br-81 is used for the production of the radioisotope Kr-81m which is used for diagnostics. Br-79 can be used for the cyclotron production of Kr-77 which decays to the radioisotope Br-77 although the most common production route for Br-77 is via Se-77. Br-77 has been suggested for radiotherapy because of it electron capture decay and ease of labeling.
Naturally occurring isotopes
Isotope | Mass/Da | Natural abundance (atom %) | Nuclear spin (I) | Magnetic moment (μ/μN) |
---|---|---|---|---|
79Br | 78.9183361 (26) | 50.69 (7) | 3/2 | 2.106399 |
81Br | 80.916289 (6) | 49.31 (7) | 3/2 | 2.270560 |
Radiosotope data
Isotope | Mass/Da | Half-life | Mode of decay | Nuclear spin | Nuclear magnetic moment |
---|---|---|---|---|---|
72Br | 71.9365 | 1.31 m | EC to 72Se | 3 | |
73Br | 72.9318 | 3.4 m | EC to 73Se | 3/2 | |
74Br | 73.92989 | 25.4 m | EC to 74Se | ||
75Br | 74.92578 | 1.62 h | EC to 75Se | 3/2 | 0.75 |
76Br | 75.92454 | 16.0 h | EC to 76Se | 1 | 0.54821 |
77Br | 76.921380 | 2.376 d | EC to 77Se | 3/2 | |
78Br | 77.921146 | 6.46 m | EC to 78Se; β– to 78Kr | 1 | 0.1 |
80Br | 79.918530 | 17.66 m | EC to 80Se; β– to 80Kr | 1 | 0.5140 |
82Br | 81.916805 | 1.471 d | β– to 82Kr | 5 | 1.6270 |
83Br | 82.915181 | 2.40 h | β– to 83Kr | 3/2 | |
84Br | 83.91651 | 31.8 m | β– to 84Kr | 2 | |
85Br | 84.91561 | 2.87 m | β– to 85Kr | 3/2 |