Name: Barium Oxide
CAS: 1304-28-5
EC Number: 215-127-9
Chemical Formular: BaO
Appearance: white solid
Molecular Weight: 153.326 g/mol
Melting Point: 1,923 °C (3,493 °F; 2,196 K)
Boiling Point: ~ 2,000 °C (3,630 °F; 2,270 K)
Density: 5.72 g/cm3, solid
Solubility in water: 3.48 g/100 mL (20 °C)
Exact Mass: 153.9 g/mol
Monoisotopic Mass: 153.9 g/mol
Topological Polar Surface Area: 17.1 A^2
Complexity: 2
MATERIAL SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1
GHS Product identifier
| Product name | Barium Oxide |
|---|
1.2
Other means of identification
| Product number | – |
|---|---|
| Other names | Barium Oxide;oxobarium; |
1.3
Recommended use of the chemical and restrictions on use
| Identified uses | Adsorbents and absorbents |
|---|---|
| Uses advised against | no data available |
1.4
Supplier’s details
| Company | Elements China Limited |
|---|---|
| Address | Building 2, No.5555, Shenzhuan Hwy, Shanghai , China |
| Telephone | +86-021-3776-2181 |
1.5Emergency phone number
| Emergency phone number | +86-021-3776-2181 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1
Classification of the substance or mixture
Acute toxicity – Category 3, Oral
Skin corrosion, Sub-category 1B
Serious eye damage, Category 1
2.2
GHS label elements, including precautionary statements
| Pictogram(s) | 
|
|---|---|
| Signal word | Danger |
| Hazard statement(s) | H271 May cause fire or explosion; strong oxidizer H301 Toxic if swallowed H314 Causes severe skin burns and eye damage |
| Precautionary statement(s) | |
| Prevention | P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… |
| Response | P301+P316 IF SWALLOWED: Get emergency medical help immediately. P321 Specific treatment (see … on this label). P330 Rinse mouth. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P316 Get emergency medical help immediately. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P317 Get medical help. |
| Storage | P405 Store locked up. |
| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
2.3
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1
Substances
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Barium Oxide | Barium oxide | 1304-28-5 | 215-127-9 |
SECTION 4: First-aid measures
4.1
Description of necessary first-aid measures
If inhaled
Fresh air, rest. Refer for medical attention.
Following skin contact
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Give one or two glasses of water to drink. Refer for medical attention .
4.2
Most important symptoms/effects, acute and delayed
Excerpt from ERG Guide 157 [Substances – Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air may release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Fire-fighting measures
5.1
Suitable extinguishing media
Excerpt from ERG Guide 157 [Substances – Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Note: Some foams will react with the material and release corrosive/toxic gases. SMALL FIRE: CO2 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam. LARGE FIRE: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
5.2
Specific hazards arising from the chemical
Excerpt from ERG Guide 157 [Substances – Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult ERG Guide 140. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. (ERG, 2016)
5.3
Special protective actions for fire-fighters
In case of fire in the surroundings, use appropriate extinguishing media.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2
Environmental precautions
Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: particulate filter respirator adapted to the airborne concentration of the substance.
6.3
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.
7.2
Conditions for safe storage, including any incompatibilities
Separated from food and feedstuffs. Dry. Well closed.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
TLV: 0.5 mg/m3, as TWA; A4 (not classifiable as a human carcinogen).MAK: (as Ba): (inhalable fraction): 0.5 mg/m3; peak limitation category: II(8); pregnancy risk group: D.EU-OEL: (as Ba): 0.5 mg/m3 as TWA
Biological limit values
no data available
8.2
Appropriate engineering controls
Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety spectacles or eye protection in combination with breathing protection if powder.
Skin protection
Protective gloves.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Solid. Powder. |
|---|---|
| Colour | White to yellowish. |
| Odour | no data available |
| Melting point/freezing point | 1 923 °C. Atm. press.:1 013 hPa. |
| Boiling point or initial boiling point and boiling range | 2000ºC |
| Flammability | Not combustible. |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | no data available |
| Auto-ignition temperature | no data available |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | in water, g/100ml at 20°C: 3.8 |
| Partition coefficient n-octanol/water | no data available |
| Vapour pressure | no data available |
| Density and/or relative density | 5.7 g/cm³. |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1
Reactivity
The solution in water is a medium strong base. Reacts violently with water, dinitrogen tetraoxide, hydroxylamine, sulfur trioxide and hydrogen sulfide. This generates fire and explosion hazard.
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
BARIUM OXIDE reacts as a strong base. Combines exothermically with all categories of acids. Reacts with carbon dioxide to form barium carbonate [Merck 11th ed. 1989]. Ignites hydroxylamine on contact [Mellor 8:291 1946-47]. Mixtures with mercurous or nickel oxide react vigorously with hydrogen sulfide in air. Explosions may result [Mellor 10:140 1946-47]. Can react, particularly in the presence of moisture, with aluminum and zinc)to form oxides or hydroxides of the metal and generate gaseous hydrogen. May initiate polymerization reactions in polymerizable organic compounds, especially epoxides. May generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, peroxides, and hydroperoxides.
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 – rat (male/female) – 132 mg/kg bw. Remarks:LD50 and 95% CL were calculated for Barium.
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the nervous system. Exposure could cause hypokalaemia. This may result in cardiac disorders and muscular disorders. Exposure could cause death.
STOT-repeated exposure
no data available
Aspiration hazard
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
SECTION 12: Ecological information
12.1
Toxicity
- Toxicity to fish: LC50 – Oncorhynchus mykiss (previous name: Salmo gairdneri) – 42.7 mg/L – 28 d.
- Toxicity to daphnia and other aquatic invertebrates: EC50 – Daphnia magna – 14.5 mg/L – 48 h. Remarks:And mortality.
- Toxicity to algae: IC50 – Lemna minor – 102 mg/L – 96 h.
- Toxicity to microorganisms: EC50 – activated sludge of a predominantly domestic sewage – > 1 000 mg/L – 3 h.
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1
UN Number
| ADR/RID: UN1884 (For reference only, please check.) | IMDG: UN1884 (For reference only, please check.) | IATA: UN1884 (For reference only, please check.) |
14.2
UN Proper Shipping Name
| ADR/RID: BARIUM OXIDE (For reference only, please check.) | IMDG: BARIUM OXIDE (For reference only, please check.) | IATA: BARIUM OXIDE (For reference only, please check.) |
14.3
Transport hazard class(es)
| ADR/RID: 6.1 (For reference only, please check.) | IMDG: 6.1 (For reference only, please check.) | IATA: 6.1 (For reference only, please check.) |
14.4
Packing group, if applicable
| ADR/RID: III (For reference only, please check.) | IMDG: III (For reference only, please check.) | IATA: III (For reference only, please check.) |
14.5
Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Barium Oxide | Barium oxide | 1304-28-5 | 215-127-9 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | Aug 27, 2020 |
|---|---|
| Revision Date | Aug 27, 2020 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS – The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home - HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en - CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg - Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp - ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Other Information
Reacts violently with fire extinguishing agents such as water.Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.
Any questions regarding this SDS, Please send your inquiry to [email protected]
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.
| Chemical Formular: | BaO |
| PubChem CID: | 62392 |
| IUPAC Name: | oxobarium |
| Inchl: | InChI=1S/Ba.O |
| InChI Key: | QVQLCTNNEUAWMS-UHFFFAOYSA-N |
| Canonical SMILES: | O=[Ba] |
| Pictogram(s): |   |
| Signal: | Danger |
| GHS Hazard Statements: | H301-H314-H332 |
| Hazard Codes: | T |
| Risk Codes: | R20-25-34 |
| Precautionary Statement Codes: | Missing Phrase – N15.00950417-P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 |
| Flash Point: | n/a |
Barium monoxide
Oxobarium
Baryta
Calcined baryta
Barium protoxide
Ketobarium
n/a
Barium is an element with atomic symbol Ba, atomic number 56, and atomic weight 137.
Barium(0) is an elemental barium.
Barium is a silvery-white metal which exists in nature only in ores containing mixtures of elements.
It combines with other chemicals such as sulfur or carbon and oxygen to form barium compounds.
Barium compounds are used by the oil and gas industries to make drilling muds. Drilling muds make it easier to drill through rock by keeping the drill bit lubricated.
They are also used to make paint, bricks, ceramics, glass, and rubber. Barium sulfate is sometimes used by doctors to perform medical tests and to take x-rays of the gastrointestinal tract.
Oxygen is the chemical element with the symbol O and atomic number 8, meaning its nucleus has 8 protons.
Oxygen is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds.
Dioxygen is used in cellular respiration and many major classes of organic molecules in living organisms contain oxygen, such as proteins, nucleic acids, carbohydrates, and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone.
Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774.
Fiber drums, steel drums, and bulk bags
