Name: Barium Bromate
CAS: 13967-90-3
EC Number: 237-750-5
Chemical Formular: BaBr2O6
Appearance: White powder
Molecular Weight: 393.13 g/mol
Melting Point: n/a
Boiling Point: n/a
Density: 3.99 g/cm3
Solubility in water: n/a
Exact Mass: 393.70936 g/mol
Monoisotopic Mass: 391.71141 g/mol
Topological Polar Surface Area: 114 A^2
Complexity: 36.5
MATERIAL SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1
GHS Product identifier
| Product name | Barium Bromate |
|---|
1.2
Other means of identification
| Product number | – |
|---|---|
| Other names | barium(2+) dibromate;UN2719;Bromic acid,barium salt |
1.3
Recommended use of the chemical and restrictions on use
| Identified uses | Industrial and scientific research uses. |
|---|---|
| Uses advised against | no data available |
1.4
Supplier’s details
| Company | Elements China Limited |
|---|---|
| Address | Building 2, No.5555, Shenzhuan Hwy, Shanghai , China |
| Telephone | +86-021-3776-2181 |
1.5Emergency phone number
| Emergency phone number | +86-021-3776-2181 |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1
Classification of the substance or mixture
Acute toxicity – Category 4, Oral
Acute toxicity – Category 4, Inhalation
2.2
GHS label elements, including precautionary statements
| Pictogram(s) |
|
|---|---|
| Signal word | Danger |
| Hazard statement(s) | H272 May intensify fire; oxidizer H302 Harmful if swallowed H332 Harmful if inhaled |
| Precautionary statement(s) | |
| Prevention | P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. |
| Response | P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P317 Get medical help. |
| Storage | none |
| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
2.3
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1
Substances
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Barium Bromate | Barium bromate | 13967-90-3 | 237-750-5 |
SECTION 4: First-aid measures
4.1
Description of necessary first-aid measures
If inhaled
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Following skin contact
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Following eye contact
Rinse with pure water for at least 15 minutes. Consult a doctor.
Following ingestion
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
4.2
Most important symptoms/effects, acute and delayed
Excerpt from ERG Guide 141 [Oxidizers – Toxic]: Toxic by ingestion. Inhalation of dust is toxic. Fire may produce irritating, corrosive and/or toxic gases. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Fire-fighting measures
5.1
Suitable extinguishing media
Excerpt from ERG Guide 141 [Oxidizers – Toxic]: SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control. LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do it without risk. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
5.2
Specific hazards arising from the chemical
Excerpt from ERG Guide 141 [Oxidizers – Toxic]: These substances will accelerate burning when involved in a fire. May explode from heat or contamination. Some may burn rapidly. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2016)
5.3
Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
6.2
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
6.3
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Handling in a well ventilated place.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
Avoid formation of dust and aerosols.
Use non-sparking tools.
Prevent fire caused by electrostatic discharge steam.
7.2
Conditions for safe storage, including any incompatibilities
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2
Appropriate engineering controls
Ensure adequate ventilation.
Handle in accordance with good industrial hygiene and safety practice.
Set up emergency exits and the risk-elimination area.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Skin protection
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Barium bromate is a white crystalline solid or powder. Slightly soluble in water and denser than water. Very toxic by ingestion or inhalation. Fire hazard when in contact with organic materials and may explode when heated above 300°F. Used as a corrosion inhibitor and to manufacture other chemicals. |
|---|---|
| Colour | no data available |
| Odour | no data available |
| Melting point/freezing point | 260(分解)ºC |
| Boiling point or initial boiling point and boiling range | no data available |
| Flammability | no data available |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | no data available |
| Auto-ignition temperature | no data available |
| Decomposition temperature | no data available |
| pH | no data available |
| Kinematic viscosity | no data available |
| Solubility | no data available |
| Partition coefficient n-octanol/water | no data available |
| Vapour pressure | no data available |
| Density and/or relative density | 3.99 g/cm3 |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1
Reactivity
Slightly soluble in water.
10.2
Chemical stability
no data available
10.3
Possibility of hazardous reactions
BARIUM BROMATE is an oxidizing agent. May react violently with combustibles and reducing agents such as textiles, oil, fat, sugar, sawdust, ammonium salts, sulfur, carbon, phosphorus, metal powders and sulfides. A combination of finely divided aluminum with finely divided barium bromate can explode by heat, percussion, or friction [Mellor 2:310 1946-47].
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
SECTION 12: Ecological information
12.1
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to
a licensed chemical destruction plant or by controlled incineration
with flue gas scrubbing. Do not contaminate water, foodstuffs,
feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and
offered for recycling or reconditioning.
Alternatively, the packaging can be punctured to
make it unusable for other purposes and then be disposed of
in a sanitary landfill. Controlled incineration
with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1
UN Number
| ADR/RID: UN2719 (For reference only, please check.) | IMDG: UN2719 (For reference only, please check.) | IATA: UN2719 (For reference only, please check.) |
14.2
UN Proper Shipping Name
| ADR/RID: BARIUM BROMATE (For reference only, please check.) | IMDG: BARIUM BROMATE (For reference only, please check.) | IATA: BARIUM BROMATE (For reference only, please check.) |
14.3
Transport hazard class(es)
| ADR/RID: 5.1 (For reference only, please check.) | IMDG: 5.1 (For reference only, please check.) | IATA: 5.1 (For reference only, please check.) |
14.4
Packing group, if applicable
| ADR/RID: II (For reference only, please check.) | IMDG: II (For reference only, please check.) | IATA: II (For reference only, please check.) |
14.5
Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Barium Bromate | Barium bromate | 13967-90-3 | 237-750-5 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Not Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Not Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | Sep 15, 2020 |
|---|---|
| Revision Date | Sep 15, 2020 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS – The International Chemical Safety Cards (ICSC), website:
http://www.ilo.org/dyn/icsc/showcard.home - HSDB – Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC – International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal – The Global Portal to Information on Chemical Substances by OECD, website:
http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en - CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG – Emergency Response Guidebook by U.S. Department of Transportation, website:
http://www.phmsa.dot.gov/hazmat/library/erg - Germany GESTIS-database on hazard substance, website:
http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp - ECHA – European Chemicals Agency, website: https://echa.europa.eu/
Any questions regarding this SDS, Please send your inquiry to [email protected]
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. We as supplier shall not be held liable for any
damage resulting from handling or from contact with the above product.
| Chemical Formular: | BaBr2O6 |
| PubChem CID: | 61706 |
| IUPAC Name: | barium(2+);dibromate |
| Inchl: | InChI=1S/Ba.2BrHO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2 |
| InChI Key: | VEASZGAADGZARC-UHFFFAOYSA-L |
| Canonical SMILES: | [O-]Br(=O)=O.[O-]Br(=O)=O.[Ba+2] |
| Pictogram(s): |   |
| Signal: | Danger |
| GHS Hazard Statements: | H272-H302-H332 |
| Hazard Codes: | O, Xi |
| Risk Codes: | R20/22 |
| Precautionary Statement Codes: | P221-P262 |
| Flash Point: | n/a |
Bromic acid barium salt
barium(2+) dibromate
Bisbromic acid barium salt
barium dibromate
Barium bromate monohydrate
n/a
Bromine is a chemical element with symbol Br and atomic number 35.
It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas.
Its properties are thus intermediate between those of chlorine and iodine.
Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek βρῶμος (“stench”), referencing its sharp and disagreeable smell.
Barium is an element with atomic symbol Ba, atomic number 56, and atomic weight 137.
Barium(0) is an elemental barium.
Barium is a silvery-white metal which exists in nature only in ores containing mixtures of elements.
It combines with other chemicals such as sulfur or carbon and oxygen to form barium compounds.
Barium compounds are used by the oil and gas industries to make drilling muds. Drilling muds make it easier to drill through rock by keeping the drill bit lubricated.
They are also used to make paint, bricks, ceramics, glass, and rubber. Barium sulfate is sometimes used by doctors to perform medical tests and to take x-rays of the gastrointestinal tract.
Oxygen is the chemical element with the symbol O and atomic number 8, meaning its nucleus has 8 protons.
Oxygen is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds.
Dioxygen is used in cellular respiration and many major classes of organic molecules in living organisms contain oxygen, such as proteins, nucleic acids, carbohydrates, and fats, as do the major constituent inorganic compounds of animal shells, teeth, and bone.
Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele, in Uppsala, in 1773 or earlier, and Joseph Priestley in Wiltshire, in 1774.
Fiber drums, steel drums, and bulk bags
