Element Selenium
It is a chemical element with the symbol Se and atomic number 34.
It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, and also has similarities to arsenic.
Element Selenium rarely occurs in its elemental state or as pure ore compounds in the Earth’s crust. Selenium (from Ancient Greek σελήνη (selḗnē) “Moon”) was discovered in 1817 by Jöns Jacob Berzelius, who noted the similarity of the new element to the previously discovered tellurium (named for the Earth).
Selenium is found in metal sulfide ores, where it partially replaces the sulfur.
Commercially, selenium is produced as a byproduct in the refining of these ores, most often during production. Minerals that are pure selenide or selenate compounds are known but rare.
Names and Identifiers
Chemical Formula: | Se |
CAS: | 7782-49-2 |
Molecular Weight: | 78.960g/mol |
EC Number : | 231-957-4 |
MDL Number: | MFCD00134090 |
Color: | gray or red (crystalline), black or red (amorphous) |
Other Names: | Selen, Selenio |
PubChem CID: | 6326970 |
IUPAC Name: | Selenium |
Inchl: | InChI=1S/Se |
InChI Key: | BUGBHKTXTAQXES-UHFFFAOYSA-N |
Canonical SMILES: | [Se] |
ICSC Number: | 0072 |
Physical & Chemical Properties
Phase: | Solid |
Density: | 4.81 g/cm³ |
Boiling Point: | 958 K (685 °C, 1265 °F) |
Melting Point: | 494 K (221 °C, 430 °F) |
Molecular Formula: | Se |
Flash Point: | n/a |
Exact Mass: | 79.916519 |
Symbol: | |
Signal Word: | Danger |
Hazard Statements: | H301 + H331-H373-H413 |
Precautionary Statements: | P261-P301 + P310-P311 |
Hazard Codes: | T:Toxic |
Risk Phrases: | R23/25;R33;R53 |
Safety Phrases: | S26-S61-S45-S28-S20/21-S28A |
RIDADR: | UN 3440 6.1/PG 3 |
WGK Germany: | 2 |
RTECS: | VS7700000 |
Packaging Group: | III |
Hazard Class: | n/a |
Selenium isotopes are mainly used for the production of medical and industrial radioisotopes.
Se-77 and Se-78 are used for the production of the therapeutic radioisotope Br-77. Se-80 is used for the production of the medical radioisotope Br-80m. Se-74 is used for the production of Se-75 which is used as a source in gamma radiography. Se-76 can be used for the production of the medical isotopes Br-75 and Br-76. Se-82 has been used to study double beta decay. Most of the Selenium isotopes have been used in studies into the role of Selenium as an essential nutrient.
Naturally occurring isotopes
Isotope | Mass/Da | Natural abundance (atom %) | Nuclear spin (I) | Magnetic moment (μ/μN) |
---|---|---|---|---|
74Se | 73.9224746 (16) | 0.89 (4) | 0 | |
76Se | 75.9192120 (16) | 9.37 (29) | 0 | |
77Se | 76.9199125 (16) | 7.63 (16) | 1/2 | 0.53506 |
78Se | 77.9173076 (16) | 23.77 (28) | 0 | |
80Se | 79.9165196 (19) | 49.61 (41) | 0 | |
82Se | 81.9166978 (23) | 8.73 (22) | 0 |
Radiosotope data
Isotope | Mass/Da | Half-life | Mode of decay | Nuclear spin | Nuclear magnetic moment |
---|---|---|---|---|---|
70Se | 69.9335 | 41.1 m | EC to 70As | 0 | |
71Se | 70.9319 | 4.7 m | EC to 71As | 5/2 | |
72Se | 71.92711 | 8.5 d | EC to 72As | 0 | |
73Se | 72.92678 | 7.1 h | EC to 73As | 9/2 | |
75Se | 74.922524 | 119.78 d | EC to 75As | 5/2 | 0.67 |
79Se | 78.918500 | 65000 y | β– to 79Br | 0 | -1.018 |
81Se | 80.917993 | 18.5 m | β– to 81Br | 1/2 | |
83Se | 82.919119 | 22.3 m | β– to 83Br | 9/2 | |
84Se | 83.91847 | 3.3 m | β– to 84Br | 0 |