Element Hafnium
Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1923, by Coster and Hevesy, making it the last stable element to be discovered. Hafnium is named after Hafnia, the Latin name for Copenhagen, where it was discovered.
Names and Identifiers
Chemical Formula: | Hf |
CAS: | 7440-58-6 |
Molecular Weight: | 178.490 g/mol |
EC Number : | 231-166-4 |
MDL Number: | MFCD00011032 |
Color: | silvery/ gray steel |
Other Names: | Afnio, Háfnio, Hafnio |
PubChem CID: | 23986 |
IUPAC Name: | Hafnium |
Inchl: | InChI=1S/Hf |
InChI Key: | VBJZVLUMGGDVMO-UHFFFAOYSA-N |
Canonical SMILES: | [Hf] |
ICSC Number: | 0847 |
Physical & Chemical Properties
Phase: | Solid |
Density: | 13.31 g/cm³ |
Boiling Point: | 4876 K (4603 °C, 8317 °F) |
Melting Point: | 2506 K (2233 °C, 4051 °F) |
Molecular Formula: | Hf |
Flash Point: | n/a |
Exact Mass: | 179.946503 |
Symbol: | |
Signal Word: | Danger |
Hazard Statements: | H228 |
Precautionary Statements: | P210 |
Hazard Codes: | T+:Verytoxic; |
Risk Phrases: | R26/27/28;R35 |
Safety Phrases: | S26-S27-S36/37/39-S45-S33-S16-S23 |
RIDADR: | UN 3178 4.1/PG 3 |
WGK Germany: | n/a |
RTECS: | n/a |
Packaging Group: | III |
Hazard Class: | 8 |
At least 34 isotopes of hafnium have been observed, ranging in mass number from 153 to 186.
The five stable isotopes are in the range of 176 to 180. The radioactive isotopes’ half-lives range from only 400 ms for 153Hf, to 2.0 petayears (1015 years) for the most stable one, 174Hf
Naturally occurring isotopes
Isotope | Mass/Da | Natural abundance (atom %) | Nuclear spin (I) | Magnetic moment (μ/μN) |
---|---|---|---|---|
174Hf | 173.940044 (4) | 0.16 (1) | 0 | |
176Hf | 175.941406 (4) | 5.26 (7) | 0 | |
177Hf | 176.943217 (3) | 18.60 (9) | 7/2 | 0.7936 |
178Hf | 177.943696 (3) | 27.28 (7) | 0 | |
179Hf | 178.9458122 (29) | 13.62 (2) | 9/2 | -0.6409 |
180Hf | 179.9465457 (30) | 35.08 (16) | 0 |
Radiosotope data
Isotope | Mass/Da | Half-life | Mode of decay | Nuclear spin | Nuclear magnetic moment |
---|---|---|---|---|---|
172Hf | 171.93946 | 1.87 y | EC to 172Lu | 0 | |
173Hf | 172.9407 | 23.6 h | EC to 173Lu | 1/2 | |
175Hf | 174.941504 | 70 d | EC to 175Lu | 5/2 | 0.54 |
181Hf | 180.949099 | 42.4 d | β– to 181Ta | 1/2 | |
182Hf | 181.95055 | 9 x 106 y | β– to 182Ta | 0 |